Carbon dioxide binary crystals via the thermal decomposition of RDX at high pressure.
نویسندگان
چکیده
A carbon dioxide and nitrous oxide solid solution has been captured in a diamond anvil cell following the thermal decomposition of 1,3,5-trinitroperhydro-1,3,5-triazine (RDX) at high temperatures and pressures. This is the first time a carbon dioxide binary solid has been observed at high pressure. This observation has stimulated low temperature crystallographic studies of this binary system using recently developed gas absorption apparatus and computational modelling.
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متن کاملCarbon dioxide binary crystals via the thermal decomposition of RDX at high pressure† †Electronic supplementary information (ESI) available: Experimental methods for the low temperature and high pressure growth and data collection. Theoretical methods are outlined together with the validation of the cluster expansion methodology. Crystallographic data tables are included. Raw data can be found at University of Strathclyde-Pure. See DOI: 10.1039/c7sc01379e Click here for additional data file.
Strathclyde Institute of Pharmacy and Biom 161 Cathedral Street, Glasgow, G4 0RE, UK School of Chemistry, Centre for Science a Edinburgh, King's Buildings, David Brewster Diamond Light Source, Harwell Science and OX11 0DE, UK † Electronic supplementary information for the low temperature and high p Theoretical methods are outlined togeth expansion methodology. Crystallographi can be found at Un...
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عنوان ژورنال:
- Chemical science
دوره 8 7 شماره
صفحات -
تاریخ انتشار 2017